HEAVY METALS
DISTRIBUTION IN THE ESTUARINE ECOSYSTEM OF BAHIA BLANCA, ARGENTINA.
The Bahía
Blanca estuary is located between 38°45’ - 39°40’ S, and 61°45’ -
62°30’ W, at the southeast coast of Buenos Aires
province, in Argentina. It has elongated shape with a lenght of 80 Km, and is
characterized by the presencie of various channels, fine sand and silt-clay
sediments. Tidal oscillations of 4m and predominant northwestern wnds create
strong tidal currents which facilitate water mixture, leading to a uniform
vertical distribution of the main oceanographic parameters. At low tide this
estuary encompasses an area of 400 Km2, and at high tide the total
area is nearly 1300 Km2. Bahía Blanca is an estuarine environment
with a very particular behavior, which includes a relatively small input of
inland water, and with several marginal areas which seasonally function as
hypersaline ones (Freije et al., 1981).
At the
northern boundaries of the estuary various ports, towns (with a population
exceeding 350.000 inhabitants) and industries are located, and several streams
and channels discharge into the area. Oil refineries and terminals,
petrochemical industries, meat factories, leather plants, fish factories,
textile plants, wool washing plants, silos and cereal mills discharge their
processing residues into the streams or directly into the estuary. This area is extensively used by fishing
boats, oil tankers and cargo vessels and therefore requires regular dredging.
The present study includes
information on the occurrence and distribution of cadmium, lead and chromium in
surface sediments, finest grain size fraction of sediments (<63µm),
dissolved and suspended particulate matter, as well as in several estuarine
organisms.
The area under study and location of sampling stations
are shown in Figure 1. The samples were taken from six sampling
stations, monthly frequency, during 1998.
Surface water samples (0,5-1 m) were collected with a
Van Dorn oceanografic bottle on deck from a position in the prow which minimized
contamination from the ship. Samples of
water were filtered through Millipore HA filters (0,45 µm pore size) for
the determination of suspended and dissolved
metals. Before use, the filters were soaked overnight in dilute HCL and stored
in redestilled water. The filtered samples were acidifed using 3 ml of HNO3.
All fractions were frozen until analysis.
Surface
sediments were obtained with a sledge and were stored in a freezer at -20°C
until their analytical treatment in the laboratory. These samples were oven at
45±5°C up to constant weight, and then subsamples were sifted, and the fraction
lower than 63 µm was removed.
Organisms samples were taken at station 6 (internal
station). Phytoplankton samples were collected using a net of 50µm size mesh.
Samples were filtered through Millipore HA filters (0,45 µm pore size)
for the determination of heavy metals. Samples of estuarine crab Chasmagnathus
granulata were collected in the intertidal zone. Organisms were disected
and soft tissues and carapace were removed. These samples were oven at 45±5°C
up to constant weight and subsequently homogenized.
The disolved
metals were simultaneously extracted from water samples by chelation with
ammonium pyrrolidine-dithiocarbamato (APDC) followed by extraction into methil
iso-butil ketone (MIBK) according to the modification of the method described
by Koirtyohann & Wen (1973).
Samples of sediments, finest grain size fraction of sediments, suspended particulate matter and organisms
were digested in a mixture of concentrated nitric and perchloric acids (3:1),
according to the method descrbed by Dalziel & Baker (1983) modified by
Marcovecchio et al. (1988).
A
Perkin-Elmer Model 2380 atomic absorption spectrophotometer with air/acetylene
flame was utilized to determine heavy metal concentrations (Cd, Pb and Cr).
Analitical grade reagents were used to built up the corresponding blanks and
calibration curves, and the analytical quality (AQ) was tested against
reference materials, provided by The National Institute for Environmental
Studies (NIES) from Tsukuba (Japan).

Figure 1. Location of sampling stations in the southern area of
Bahía Blanca estuary.
The distribution of cadmium, lead and chromium in surface sediments,
finest grain size fraction of sediments (<63µm), dissolved and suspended
particulate matter, are showed in
the Figures 2, 3 and 4, respectively. The heavy metal concentrations in
phytoplancton and estuarine crab are
showed in Table 1.
No dissolved chromium levels were detected in the study
area. Moreover, dissolved Cd and Pb, have presented distributions with
different range of concentration values but with similar trends. Thus cadmium
contents have varied between 0.29 and 0.69 µg/L; those of lead did between 1.96
and 3.51 µg/L; highest values for these metals are found in the station #4
(“oil terminal”). Cadmium and lead levels of the present study are in the same
order of magnitude than those found previously in the same area, ten years ago
(Pucci, 1988).
The concentrations of particulate trace metals (Cd, Cr
and Pb) were measured. Cadmium contents have varied between 3.32 and 5.88 µg/g,
dry wt.; those of chromium ranged between 5.47 and 8.91 µg/g, dry wt.; while
those of lead did between 30.29 and 55.0 µg/g, dry wt. The values of all trace
metals as reported in the present paper have clearly agreed with those
presented as natural background ones for different regions all over the world
by several authors (i.e., Harper, 1991; Lewis et al.,1992).
The studied
metals in surface sediments have presented distribution with diferent range of
concentrations but with similar trends; highest values for these metals are
found in the station #3 (“White harbour”) and the minimum at station 1
(external). Thus, cadmium concentrations have varied between 0.60 and 1.64
µg/g, dry wt.; those of chromium ranged between 4.14 and 8.93 µg/g, dry wt.;
while those of lead did between 8.67 and 18.33 µg/g, dry wt.
Trace metals
distribution in finest grain size fraction of sediments not present great
variations, especially cadmium and chromium levels. Cadmium contents ranged
between 2.01 and 2.34 µg/g, dry wt.; those of chromium have varied between
10.87 and 11.69 µg/g, dry wt.; while those of lead did between 24.35 and 36.08
µg/g, dry wt. Chromium values reported in the present study agree with those
reported from non industrial areas, while Cd and Pb content agree with those
reported from industrial areas (Lacerda et al., 1988).

Figure 2. Cadmium distribution in differents fractions: dissolved (µg/L); SPM,
surface sediments and fine grain size fraction (µg/g, dry wt.).

Figure 3. Chromium
distribution in differents fractions: SPM, surface sediments and fine grain
size fraction (µg/g, dry wt.).

Figure 4. Lead distribution in
differents fractions: dissolved (µg/L); SPM, surface sediments and fine grain
size fraction (µg/g, dry wt.).
Table 1. Heavy metal concentrations in phytoplancton samples and tissues of
estuarine crab (wide carapace: 25-30 mm), expressed in µg/g, dry wt. N.d.=non
detectable.
|
|
Cd |
Cr |
Pb |
|
|
Phytoplancton n=12 |
0.81 |
8.22 |
11.14 |
|
|
Estuarine crabs n=23 |
Soft tissue |
0.96 |
0.95 |
n.d. |
|
Carapace |
5.15 |
0.78 |
3.06 |
|
The process of transference of both
essential and non-essential metals to estuarine organisms has been observed in
Bahía Blanca. Metal contents in phytoplankton samples were close to 1000 times
higher than those recorded for the neighbouring estuarine water, which has
indicated the occurrence of an accumulation process. This fact is extremely
important, keeping in mind phytoplankton is the basis of the corresponding
trophic web.
Table 1 shows Cd and Pb concentrations in crab carapaces,
possible detoxification way during the moult time. The occurrence of both
cadmium and lead in samples of phytoplankton and crabs (Chasmagnathus
granulata) was significant, considering they are non essential metals.
Acknowledgements: This paper have information belongs to Doctoral
Thesis of Lic.S.Andrade and Lic.L.Ferrer, to be presented at Universidad
Nacional del Sur (Bahía Blanca, Argentina).
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